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国家自然科学基金(60501009)

作品数:4 被引量:11H指数:2
相关作者:顾宁马明张宇更多>>
相关机构:东南大学更多>>
发文基金:国家自然科学基金国家重点基础研究发展计划更多>>
相关领域:理学电子电信一般工业技术化学工程更多>>

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Magnetic nanocomposites of Fe_3O_4/SiO_2-FITC with pH-dependent fluorescence emission被引量:1
2009年
This paper describes the formation of magnetic and fluorescent nanocomposite particles which consist of superparamagnetic Fe3O4 core, SiO2 shell and organic dye (FITC) coating layer on their surface. The obtained nanocomposites possess typical superparamagnetism and exhibit clear green fluorescence image. And their fluorescence emission is pH-dependent, which would be applied to pH sensing. ?2009 Yu Zhang. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All fights reserved.
Yu ZhangShang Wen Yan GongLu JinShuang Man LiZhong Ping ChenMing MaNing Gu
关键词:NANOCOMPOSITESFLUORESCENCE
Temperature-dependent photoluminescence of highly luminescent water-soluble CdTe quantum dots被引量:2
2009年
Highly luminescent water-soluble CdTe quantum dots (QDs) have been synthesized with an electrogenerated precursor. The obtained CdTe QDs can possess good crystallizability, high quantum yield (QY) and favorable stability. Furthermore, a detection system is designed firstly for the investigation of the temperature-dependent PL of the QDs. ?2009 Yu Zhang. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
Ji Wei LiuYu ZhangCun Wang GeYong Long JinSun Ling HuNing Gu
Facile synthesis of gold nanoplates by thermally reducing AuCl_4^- with aniline被引量:1
2009年
We herein report a one-step, wet-chemical approach to synthesizing gold nanoplates in large quantities via the AuCl4^- thermal reduction process by aniline, without introducing additional capping agent or surfactant. It is found that the reduction kinetics of AuCl4^- is greatly altered by varying the initial molar ratio of aniline to AuCl4^-. Moreover, further investigation reveals that the insitu formed polyaniline could serve effectively as a capping agent to preferably adsorb the { 1 1 1 } facets of gold crystals during a slow reduction process, directing the formation of gold nanoplates.
Kang Xu
关键词:ANILINE
反胶束体系中Fe_3O_4/SiO_2核壳结构纳米粒子的制备和表征被引量:7
2009年
在反胶束体系中制备Fe3O4/SiO2核壳结构纳米粒子,并利用透射电子显微镜表征颗粒的结构和形貌.首先,在水体系中采用共沉淀法制备平均粒径为13nm的Fe3O4纳米粒子,并用有机小分子柠檬酸对其进行表面修饰,加入氨水后形成稳定的Fe3O4胶体溶液.然后,将此胶体溶液作为水相滴加到Triton X-100/环己烷/正丁醇的表面活性剂/油相/助表面活性剂溶液体系中,搅拌后形成稳定的油包水反胶束体系.在反胶束内以氨水为催化剂,使正硅酸乙酯水解,从而获得SiO2包覆的Fe3O4核壳结构纳米粒子.实验结果表明,改变水和表面活性剂Triton X-100的浓度比ω,可以达到调控核壳结构纳米粒子形貌的目的.当ω=9时,可获得尺寸均匀、平均粒径约为100nm的Fe3O4/SiO2核壳结构纳米粒子.
马明张宇顾宁
关键词:四氧化三铁二氧化硅反胶束
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