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国家自然科学基金(s51072223)

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Effect of 6H-SiC (1120) substrate on epitaxial graphene revealed by Raman scattering
2013年
A nonpolar SiC(1120) substrate has been used to fabricate epitaxial graphene (EG). Two EGs with layer numbers of 8-10 (referred to as MLG) and 2-3 (referred to as FLG) were used as representative to study the substrate effect on EG through temperature-dependent Raman scattering. It is found that Raman lineshifts of G and 2D peaks of the MLG with temperature are consistent with that of free graphene, as predicted by theory calculation, indicating that the substrate influence on the MLG is undetectable. While Raman G peak lineshifts of the FLG to that of the free graphene are obvious, however, its lineshift rate (-0.016 cm-1/K) is almost one third of that (-0.043 cm-1/K) of an EG on 6H-SiC (0001) in the temperature range from 300 K to 400 K, indicating a weak substrate effect from SiC (1120) on the FLG. This renders the FLG with a high mobility around 1812 cm2.V-1 .s -1 at room temperature even with a very high carrier concentration about 2.95 × 10 ^13 cm-2 (p-type). These suggest SiC (1120) is more suitable for fabricating EG with high performance.
林菁菁郭丽伟贾玉萍陈莲莲芦伟黄郊陈小龙
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