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国家自然科学基金(s20804047)

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发文基金:国家自然科学基金国家重点基础研究发展计划更多>>
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SELF-ASSEMBLY OF LINEAR ROD-COIL MULTIBLOCK COPOLYMERS被引量:2
2013年
The self-assembly of the linear rod-coil multiblock copolymers is studied by applying self-consistent-field lattice techniques in a three-dimensional (3D) space. Compared to the copolymer with one rod, the copolymer with more rods (mrod≥ 2) exhibits rich order-order phase transitions with increasing temperature, where the ordered morphology changes from strips to perforated lamellae and finally to lamellae. In addition, taking the copolymer with mrod = 2 as a representative, we fiarther study the effects of the volume fractions of the rods, the spacer coils and the end coils on the phase behaviors respectively, by which the detailed self-assembled mechanism of the linear rod-coil multiblock copolymers is revealed. Our results are expected to provide guidance for the design of the rod-coil materials.
Ying-dong XiaJi-zhong ChenTong-fei ShiLi-jia An
关键词:SELF-ASSEMBLY
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